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Rate of cooling of Water | Thermal Conductivity of Insulating Materials

RESEARCH QUESTION

How does the rate of cooling of hot water depend on the thermal conductivity of the selected insulating materials?

INTRODUCTION

Insulators are materials that inhibit the property of resisting electricity and heat. The idea of insulators sparked in my mind while referring a journal which discusses why a person feels warm even while wearing a light weight cloth. This discussion was based on the concept of heat transfer. In the chapter thermal physics, I remember the concept of heat transfer being discussed. My teacher introduced a concept called thermal conductivity to give more clarity and understanding about heat transfer. I decided to choose this topic because the concept of thermal insulation is very much used in our daily life. The cloths we wear, the buildings that are built, the mechanical systems that are manufactured, in automobiles, in electrical systems, mostly everywhere we see the application of thermal insulation. This sparked a curiosity in me to know how different materials insulate heat differently.

In order to investigate this, I decided to conduct an experiment by building an apparatus of my own design to determine the best thermal insulator among the chosen materials. Four commonly known materials that most of us have come across were chosen for the experiment. The materials chosen are cement, mud (which is used in the production clay tiles), Plaster of Paris  and saw dusts which are in powder form. The cooling rate of hot water will be observed with the selected insulating material and thus qualitatively determining the best insulator which makes the hot water to cool very slowly.  The temperature readings were taken using Vernier temperature probe and the data collection through Logger Pro, a software interface. All the data collections were automated with the help the software interface.

BACKGROUND information

The underlying principle of this experiment is thermal conductivity. by comparing the thermal conductivity the effectiveness of different materials as an insulator can be compared. The material with the least thermal conductivity is considered as a good insulator and the material with higher thermal conductivity is a good conductor of heat[2]. According to law of thermal conductivity, the thermal conductivity of a material can be expressed as:



Here, k represents the thermal conductivity value. from the equation it can be said that the amount of heat energy (Q) is directly proportional to the surface area, temperature difference and inversely proportional to the distance between the opposite sides of the insulator[2]. From the values obtained through the data collection, a temperature v/s time graph will be plotted for the analysis. the obtaining graph is expected to be an exponential curve based on the principle of Newtons law of cooling[3]. By linearizing the graphs, the curve which gives the least slop will be the best insulator.


HYPOTHESIS

the thermal insulation property increases with decrease in thermal conductivity

VARIABLES

·       Independent variables: Time(s)

·       Dependent variables: Temperature (°C)

·       Controlled variables:

1.     The distance between the plastic and metallic container: This parameter was made constant because according to the law of thermal conductivity, the rate at which the heat flows through a material is directly proportional to the area through which it flows[2].

2.     The mass of water taken to heat: The amount of heat released depends on the amount of water taken based on the concept of specific heat capacity. Mass is directly proportional to the amount of energy released or absorbed[4]

METHOD

Apparatuses Required:

1.     Cylindrical plastic container of 5 cm radius

2.     Cylindrical copper container with the same height that of the plastic container and of radius 2 cm

3.     Plaster of Paris, 500g (Fig. A)

4.     Mud, 500g (Fig. B)

5.     Cement powder, 500g (Fig. C)

6.     Saw dust, 500g (Fig. D)

7.     Temperature probe

8.     Hot water

9.     Bunsen burner

10.  Insulating lid with same radius that of the plastic container.

11.  Vernier lab quest Logger Pro (software interface for data-collection)



Experimental set-up


Schematic diagram 



Experimental procedure

1.     The copper container was placed inside the plastic container as shown in Fig. F. It was placed equidistant from all the sides of the plastic container for uniform heat distribution.

2.     The remaining gap between the plastic container and the copper container were filled with the insulating material.

3.   The hot water having a temperature around  was poured into the copper container.

4.     Both the containers were covered with a thermocol lid which was fit inside the cap of the plastic container. This was done in order to provide maximum insulation such that the heat energy is not lost through any air gap and also such that the plastic lid doesn’t absorb the heat.

5.     The temperature probe was fixed in a hole which was provided on the insulating lid and connected to the vernier lab quest and to the laptop as shown in Fig. E.

6.     A continuous data collection was begun when the temperature reading was shown as  in the Logger Pro.

7.     The above procedures were repeated for different insulating materials.

8.    The time for every  change from  was recorded.

Precautionary measures

1.     It was made sure that there is enough gap between the plastic and copper containers such that the plastic container does not conduct the radiated heat from the copper container.

2.     It was made sure that the gap between the plastic and copper containers is kept constant for all the trials and with other insulating materials.

3.     Packing of the insulating materials into the gaps was done uniformly for all the trials. This includes making sure that there is not air gap between the containers where the insulating materials are packed.

4.     The insulating lid was tightly fit in order to minimize heat loss.

5.     It was made sure that the insulating material after the trial was kept outside for cooling such that it attains the room temperature. 

6.     Safety goggles and gloves were worn since the experiment dealt with hot water and heater.


DATA collection






DATA PROCESSING

The table shown below (TABLE 5) gives the average time taken for the hot water to cool down by a factor of  and as well as the standard deviation with the different insulating materials.



Error calculation

The calculated error values shown in TABLE 6 are for the time taken for every  change from 80 degree celsius to 60.



Graphs 

The TABLE 7 shown below represents the average time taken for every  change with its uncertainty values for all the four selected insulating materials. Based on this table are the graphs shown below with the error bars.



Linearization of the graphs

Since the obtained graphs are of exponential form as expected, the linearization of the graphs was done by taking the log value of the y-axis i.e. the log value of the temperature and the time on x-axis. The TABLE 8 shown below gives the log values of the temperature. The TABLE 9 shown below is the slop values of the linearized curves. The curve giving the least slope will be the best insulator and the curve with the maximum slope will be a good thermal conductor. The modulus of the slopes is taken in order to remove the negative sign. 

                                                                    TABLE 8

Temperature ( )

80

75

70

65

60

Log (Temperature)

1.903

1.875

1.845

1.813

1.778





CONCLUSION

From the data collection and data processing it can be concluded saw dust is comparatively the best insulator and mud is the least insulating material. This was confirmed using   GRAPH 6. The steepness of the exponential curve can give a qualitative result about the rate of cooling of the water kept in the copper container with respect to each insulating material used. Greater the steepness, higher the rate of cooling and lesser the steepness of the curve, the better insulator it is due to the lesser cooling rate. The curve produced by mud was very steep compared to curves of other insulating materials. In the same way the curve of saw dust had the least steep. Therefore, the saw dust resulted in being a better insulator. To study the linear relationship between temperatures and time of the respective insulating material a graph log (temperature) v/s time was plotted for each material. A linear best fit was inserted into the graph to obtain the slope of the linearized graph. The slope of the linearized graphs gave an idea about the rate of cooling and thus determining the best insulator. The graph with the least slope will be a good insulator and the graph with the highest slope will be a bad insulator. From TABLE 9 it can be seen that the graph of saw dust gave the least slope resulting in being a good insulator of heat. The graph of mud gave the highest slope which results mud being a bad insulator of heat. Therefore, from TABLE 9 and GRAPH 6, I can also arrange the selected insulating materials in the order of decreasing thermal conductive property as:

EVALUATION

This investigation was very successful in determining the best insulating material among the selected ones. I am very confident with the obtained results. The average percentage uncertainty values for all the insulating materials were less than 10% except for the material mud, 18.2%. In TABLE2, all the values obtained for trial 3 & 4 are comparatively very much away from the values obtained for trial 1, 2 & 5. The deviations in the value are due to the experimental error (random error). From TABLE 5 I observed that the values obtained in each trial were deviated from the mean value by a factor of 50 to 178 seconds for certain trials especially with saw dust mud. I assume it to happen due to the initial temperature of the hot water. According to law of thermal conductivity, the temperature difference between the system and surrounding affects the rate of heat transfer. Higher the value of  (temperature difference), higher the rate is i.e. if the cooling begins from higher temperatures, the system cools quickly comparatively from lower temperatures[2], [3]. I remember while conducting the experiment the initial temperature readings for all the trials was different. Some started cooling from  and few others from  In fact, for mud in trial 3 & 4, the initial temperatures were closer to . This would have been the experimental error that resulted in higher percentage uncertainty for mud. Other possible chances of error may be due to any potential chances of structural decomposition since I reused the material for all trials. With plaster of paris there is a potential for error to occur. Plaster of Paris  is a chemical compound that contains water of crystallization. Due to the heat absorbed from the copper container, the sample could have lost its water of crystallization and resulted in different time period for cooling[5]. In the same way cement, a mixture of oxides of calcium, aluminium and iron (III) may also have undergone slight decomposition. From all the graphs it is observed that the obtained points are lying very much close to the best fit curve. This shows the level accuracy in my obtained results. The possible chances for these deviations from the best fit will be due to the systematic error such that the inefficiency of my apparatus to provide a very good insulation capacity and the error of the temperature probe used. The obtained trend shown in the conclusion was cross checked with secondary sources and it supports the obtained trend too. From two journals that I referred it was seen that saw dust used as intermediate in the making of POP (plaster of paris) blocks and mud blocks Saw dust having a very low thermal conductivity value is mixed with materials such as Plaster of Paris and clay blocks to enhance their thermal insulation capacity[6], [7]. Since saw dust had relatively the least thermal conductivity value, it was used in other materials to enhance their thermal insulation property. This confirms the fact that saw dust being the best insulator according to the obtained trend. From a journal that discusses the thermal characteristics of cement blocks and mud blocks, it was seen that cement block has low thermal conductivity value compared to the mud block[8] which further supports the obtained trend. Journals discussing the thermal characteristics between cement and plaster of paris weren’t available. However, it is seen that plaster of paris coating is done on concrete walls which provides a protection against fire hazards[9]. This shows that plaster of paris has a good thermal insulation property compared to the concrete walls made by cement which supports the obtained trend.     

BIBLIOGRAPHY

[1]      Y. Ke and F. Wang, “Warmth without the weight,” Eng. High-Performance Text., no. 1983, pp. 231–245, 2017.

[2]      Khan, “What is thermal conductivity? (article) Khan Academy,” Khan Academy, 2015. [Online]. Available: https://www.khanacademy.org/science/physics/thermodynamics/specific-heat-and-heat-transfer/a/what-is-thermal-conductivity. [Accessed: 27-Feb-2020].

[3]      M. Kleiber, “A New Newton ’ s Law of Cooling ? Author ( s ): Max Kleiber Published by : American Association for the Advancement of Science Stable URL : https://www.jstor.org/stable/1735031,” vol. 178, no. 4067, pp. 1283–1285, 2019.

[4]      K. A. Tsokos, Physics for the IB Diploma, Sixth Edit. Cambridge University Press, 2014.

[5]      E. Onder and N. Sarier, “Thermal regulation finishes for textiles,” in Functional Finishes for Textiles: Improving Comfort, Performance and Protection, Elsevier Inc., 2015, pp. 17–98.

[6]      R. Jasim, A. Karawi, T. M. Borhan, M. Qasim, A. Karawi, and N. Al-, “STUDY THE EFFECT OF SAWDUST CONTENT AND TEMPERATURE ON FUNDAMENTAL PROPERTIES OF PLASTER MORTARS,” vol. 54, no. 4, 2019.

[7]      E. Bwayo and S. K. Obwoya, “Coefficient of Thermal Diffusivity of Insulation Brick Developed from Sawdust and Clays,” vol. 2014, 2014.

[8]      B. J. Adekoya, “THERMAL CHARACTERISTICS OF LATERITE-MUD AND CONCRETE-BLOCK FOR THERMAL CHARACTERISTICS OF LATERITE-MUD AND CONCRETE-BLOCK FOR WALLS IN BUILDING CONSTRUCTION IN,” no. March, 2014.

[9]      The Editors of Encyclopaedia Britannica, “plaster of paris | Definition, Uses, & History | Britannica.” [Online]. Available: https://www.britannica.com/technology/plaster-of-paris. [Accessed: 27-Feb-2020].












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